The two use classes, briefly
Class C3 is an ordinary dwellinghouse: a household. Class C4 is a small house in multiple occupation — broadly, three to six unrelated people sharing basic amenities.
Nationally, moving between the two is often permitted development, which is why the conversion of family houses into shared lets can happen without any planning application. Authorities that want to manage the concentration of shared housing in a particular area withdraw that right, and the withdrawal shows up as an entry on the local land charges register.